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極危 Critically Endangered
- Aythya baeri (Radde, 1863) 青頭潛鴨
- Cinnamomum kotoense Kanehira & Sasaki, 1930 蘭嶼肉桂
- Citrus taiwanica Tanaka & Shimada, 1962 南庄橙
- Cryptocarya elliptifolia Merr., 1919 菲律賓厚殼桂
- Cypripedium segawae Masam., 1933 寶島喜普鞋蘭
- Diospyros vaccinioides Lindl., 1825 楓港柿
- Eretmochelys imbricata Conant, 1991 玳瑁
- Euonymus pallidifolia Hayata, 1913 淡綠葉衛矛
- Geothelphusa lanyu Shy Ng & Yu, 1994 蘭嶼澤蟹
- Geothelphusa lutao Shy Ng & Yu, 1994 綠島澤蟹
- Grus leucogeranus Pallas, 1773 白鶴
- Isoetes taiwanensis DeVol, 1972 臺灣水韭
- Lithocarpus formosana (Skan) Hayata 臺灣石櫟
- Manis pentadactyla subsp. pentadactyla Linnaeus, 1758 穿山甲
- Oncorhynchus formosanus (Jordan & Oshima, 1919) 臺灣鉤吻鮭
- Onychoprion fuscata nubilosus (Linnaeus, 1766) ChineseCrestedTern
- Paulownia kawakamii Ito, 1912 白桐
- Pinanga tashiroi Hayata, 1913 山檳榔
- Quercus repandifolia J. C. Liao 波葉櫟
- Thalasseus bernsteini (Schlegel, 1863) 黑嘴端鳳頭燕鷗
